Pinner reaction wiki
WebbNational Center for Biotechnology Information WebbThe Pinner reaction refers to the acid catalysed reaction of a nitrile with an alcohol to form an imino ester salt (alkyl imidate salt); this is sometimes referred to as a Pinner salt. The reaction is named after Adolf Pinner, who first described it in 1877. Pinner salts are themselves reactive and undergo additional nucleophilic additions to give various useful …
Pinner reaction wiki
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Webb15 sep. 2010 · The transformation of nitriles into imidines or their salts by the treatment of nitriles with an excess of strong acid and one equivalent of alcohol followed by an … WebbThe Pinner reaction refers to the acid catalysed reaction of a nitrile with an alcohol to form an imino ester salt (alkyl imidate salt); this is sometimes referred to as a Pinner salt. The …
WebbThe Pinner reaction refers to the acid catalysed reaction of a nitrile with an alcohol to form an imino ester salt (alkyl imidate salt); this is sometimes referred to as a Pinner salt. The … Webb28 mars 2024 · The Pinner reaction refers to the acid catalysed reaction of a nitrile with an alcohol to form an imino ester salt ; this is sometimes referred to as a Pinner salt.[1] The …
Webb12 dec. 2024 · The Pinner reaction refers to the acid catalysed reaction of a nitrile with an alcohol to form an imino ester salt (alkyl imidate salt); this is sometimes referred to as a Pinner salt. The reaction is named after Adolf Pinner, who first described it in 1877. Pinner salts are themselves reactive and undergo additional nucleophilic additions to give … WebbIn the absence of additional solvents, a novel procedure was implemented for the synthesis of trimethylorthoesters through the Pinner reaction.At 5 °C, the reaction of both aliphatic and aromatic nitriles (RCN; R = Et, Bu, Ph) with a moderate excess of MeOH and gaseous HCl gave the corresponding imidate hydrochlorides [RC(NH)OR′·HCl] in excellent yields …
WebbThe Pinner reaction has been very widely used to prepare primary amidines. A modification of the Pinner synthesis involves the formation of thioimidic ester ( 3) ( Scheme 1 ). …
WebbCategory:Pinner reaction From Wikimedia Commons, the free media repository Media in category "Pinner reaction" The following 11 files are in this category, out of 11 total. … hyperion rpiWebbPinner reaction (Q376046) From Wikidata. Jump to navigation Jump to search. chemical reaction. edit. Language Label Description Also known as; English: Pinner reaction. chemical reaction. Statements. instance of. name reaction. 0 references. named after. Adolf Pinner. 0 references. Commons category. Pinner reaction. 0 references. hyperion rtWebbThe Pinner Reaction is the acid-catalyzed reaction of a nitrile with an alcohol to afford an imino ester salt that may undergo nucleophilic addition with a v... hyperion rusturnedWebbDen Pinner-reaktion är reaktionen av en nitril med en alkohol med syra katalys. Den bildade produkten är ett salt av en imidoester , som ibland kallas Pinners salt. Detta salt kan … hyperion rp gtaWebbPinner reaction Transformation of a nitrile into an imino ether, which can be converted to either an ester or an amidine. aryl R = Me, Et, 1° and 2° alkyl, aryl HX = HCI, HBr solvent CHCI3, benzne, nitrobenzene, dioxane, (EtOH, MeOH) base NaHCOs, Na2COs acid HCI, H2SO4 The first stereoselective total synthesis of AI-77B, a gastroprotective substance, … hyperion rv dumpWebb12 apr. 2024 · Die Pinner-Reaktion ist eine Namensreaktion der organische Chemie. Die Hauptanwendung der Pinner-Reaktion ist die Herstellung von Carbonsäuren, Estern, … hyperion runes of magicWebbDie Pinner-Reaktion ist eine Namensreaktion der organische Chemie. Die Hauptanwendung der Pinner-Reaktion ist die Herstellung von Carbonsäuren , Estern , … hyperions actress