WebAbstract. Deprotonation reactions of cyclophosphazenes containing secondary amino groups in the side chain lead to a doubly bridged tricyclophosphazene structure or … WebCyclotriphosphazene derivatives containing a P–NHR group in the side-chain react in the presence of a strong base to form stable intermolecular bridged products. …
High-Temperature Auto-Cross-Linking …
WebFeb 18, 2024 · In this paper, a new 100% water-soluble cyclotriphosphazene-based bridged naphthalene material (4) was prepared as a small molecule fluorescent sensor … WebNov 1, 2024 · In this study, we synthesized cyclotriphosphazene-bridged periodic mesoporous organosilica (PMOPZ) for the first time. Afterwards, PMOPZ was integrated … bear standing up
Bridged cyclophosphazenes resulting from deprotonation …
WebCyclotriphosphazene derivatives containing a P–NHR group in the side-chain react in the presence of a strong base to form stable intermolecular bridged products. Reaction of sodium hydride with mono-spiro cyclophosphazene derivatives having a P–NH group, N 3 P 3 Cl 4 [O(CH 2) 3 NH], (1a) or N 3 P 3 Cl 4 [CH 3 N(CH 2) 3 NH], (1b) leads to formation … WebThe crystal structure of an unusual cyclophosphazene-bridged dicopper complex [H 2 dmpz][(CuCl 2) 2 {N 3 P 3 O(dmpz) 5}](Hdmpz = 3,5-dimethylpyrazole) has been determined: space group P, a= 11.640(3), b= 14.497(14), c= 14.775(3), α= 77.62(6), β= 82.10(2), γ= 74.88(6)°, and Z= 2. The geometry around both copper atoms is a distorted … WebTriple diamino-bridged cyclotriphosphazene (1) was reacted in a 1:8 stoichiometry with the sodium derivatives of long-chain diols [1-octanol, 1-decanol, 1-dodecanol, 1 … diana vinjamuri