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WebJan 6, 2024 · Activation and selective functionalization of inert C(sp3)–H bonds remain one of the most challenging tasks in current synthetic chemistry. Herein, by decorating vanadium(VIV)–porphyrin into metal–organic frameworks (MOFs) to stabilize the active tertbutyl peroxide radical, we reported a new approach to accomplish inert C(sp3)–H … WebThree-dimensional architectures constructed via coordination of organic ligands to metal ions (broadly termed metal–organic frameworks, MOFs), are highly interesting for many demanding applications such as gas adsorption, molecular separation, heterogeneous catalysis, molecular sensing, etc. Being constructed from heterogeneous components, … matsumoto castle history
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